WebApr 6, 2024 · Porous organic cages (POCs) are a relatively new class of low-density crystalline materials that have emerged as a versatile platform for investigating molecular recognition, gas storage and separation, and proton conduction, with potential applications in the fields of porous liquids, highly permeable membranes, heterogeneous catalysis, … WebGraphical Abstract. Stay in shape: A large shape-persistent [4+6] amide cage has been synthesized in 21 % yield by transforming an imine cage in just two steps, using a …
Tunable Cage-Based Three-Dimensional Covalent Organic Frameworks CCS Chem
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Purely Covalent Molecular Cages and Containers for …
WebJan 16, 2024 · Coordination chemistry is a powerful method to synthesize supramolecular cages with distinct features that suit specific applications. This work demonstrates the synthesis of discrete, homochiral Fe II 2 L 3 cages via chirality-driven self-assembly. Specifically, the installation of chirality – at both the vertices and ligand backbones – … WebWe present here a simple method for the bottom-up fabrication of microporous organic particles with surface areas in the range 500–1000 m2 g–1. The method involves chiral recognition between prefabricated, intrinsically porous organic cage molecules that precipitate spontaneously upon mixing in solution. Fine control over particle size from 50 … WebMar 16, 2015 · Cage 1 showed a ~20-fold fluorescence enhancement over the free ligand at a concentration of 10.0 µM, whereas a ~24-fold fluorescence enhancement was observed for cage 2 at the same concentration ... porsche turbo s 2017